Physical meaning of orthogonality of wave functions...
During wave spreading at the water surface, the waves are orthogonal, when they doesn't intefere, i.e. when coming from mutally perpendicular directions. For example the electrons of the opposite spin numbers, occupying the very same energy level (orbital) around atom. When these wave functions of these two electrons aren't orhogonal, they coincide and the probaility of one particle is complement of the other one.
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